I'm glad the latex caulk worked out for you. It's always done well for me. I'm a big fan of styrene for roads although others here have done a fine job with other materials.
For asphalt roads in the desert, I'd spray a base coat with a mix of 80% Floquil Weathered Black and 20% SP Lark Gray. That should give you a good base coat. Try it on some scrap styrene first and adjust the mix until you get a color that looks "right".
Next, I would use chalks to darken up the center of the road and lighten up the tire travel areas in each lane. The tire travel areas take on a shine, especially in the desert, so a light brushing of glosscote after you seal the chalks with dullcote will highlight the area where the asphalt is polished by the tires and weathered by the sun. If you can, go out to an asphalt road and actually look at the color and texture. Pictures tend to make asphalt look too smooth and even when it's really a little bumpy and grainy. One of the tricks I've used in the past is to lightly sprinkle the bare styrene with very fine ballast or beach sand. It doesn't have to be much, just so the coating suggests a texture. Paint right over it and it will make your road look a little better.